An overview of technologies suitable for handling Indonesian agricultural soils contaminated with persistent organic pollutants
DOI:
https://doi.org/10.15243/jdmlm.2022.092.3415Keywords:
base, calcium, catalyst, dehalogenation, POPsAbstract
Since Indonesia have signed and ratified Stockholm Convention on Persistent Organic Pollutants (POPs) in 2009, the country must make efforts to manage POPs appropriately. A number of pollution evident of POPs has occurred in Indonesia, either air, soil or water. Agricultural soils are not excluded from POPs pollution as the result of halogenated pesticide uses or other unidentified sources. Contamination of POPs to humans have been detected, as well as indicated potential exposure of POPs to humans. Based-catalyzed decomposition is a method that can be used to decompose or decontaminate POPs. Limestone can be processed to produce calcium-based catalyst that can apply for POPs decomposition. Indonesia is a country rich in limestone natural resources to produce calcium. However, calcium is inferior to sodium or potassium in reactivity for the dehalogenation of POPs. Thus, more evaluation is needed in order for synthesizing proper and economical calcium-based catalyst to alleviate POPs pollution in Indonesia.References
Adeyemo, A.A., Adeoye, I.O. and Bello, O.S. 2012. Metal organic frameworks as adsorbents for dye adsorption: overview, prospects and future challenges. Toxicological & Environmental Chemistry 94:1846-1863, doi:10.1080/02772248.2012.744023.
Agapkina, G.I., Brodskiy, E.S., Shelepchikov A.A. and Artukhova A.M. 2017. Transformation and form of dichlorodiphenyltrichloroethane applied to Moscow soils. Moscow University Soil Science Bulletin 72(3):125-131
Akhondi, M. and Dadkhah A.A. 2018. Base-catalysed decomposition of polychlorinated biphenyls in transformer oils by mixture of sodium hydroxide, glycerol and iron. Royal Society Open Science 5:172401, doi:10.1098/rsos.172401.
Ang, E.L., Zhao, H. and Obbard, J.P. 2005. Recent advances in the bioremediation of persistent organic pollutants via biomolecular engineering. Enzyme and Microbial Technology 37:487-496, doi:10.1016/j.enzmictec.2004.07.024.
Aqliliriana, C.M., Ernee, N.M. and Irmawati, R. 2015. Preparation and characterization of modified calcium oxide from natural resources and their application in transesterification of palm oil. International Journal of Scientific & Technology Research 4(11):168-175.
Aziz, M. 2010. Limestone: added value improvement and specification for industries. Jurnal Teknologi Mineral dan Batubara 6(3):116-131 (in Indonesian).
Azrague, K. and Osterhus S.W. 2009. Persistent organic pollutants (POPs) degradation in natural waters using a V-UV/UV/TiO2 reactor. Water Science & Technology: Water Supply 9(6):653-660.
Baran, W., Makowski, A. and Wardas, W. 2008. The effect of UV radiation absorption of cationic and anionic dye solutions on their photocatalytic degradation in the presence TiO2. Dyes and Pigments 76(1):226-230, doi:10.1016/j.dyepig.2006.08.031.
Berger M. No Year. What is a MOF (metal organic framework)?. Available from https://www.nanowerk.com/mof-metal-organic-framework.php.
Brodskiy E.S., Shelepchikov A.A., Feshin D.B., Agapkina G.I. and Artukhova M.V. 2016 Content and distribution pattern of dichlorodiphenyltrichloroethane (DDT) in soils of Moscow. Moscow University Soil Science Bulletin 71(1):27-34
Centre for Industry Education Collaboration. 2017. The Essential Chemical Industry Online – calcium carbonate. Department of Chemistry. University of York. York. UK.
Collings A.F., Farmer A.D., Gwan P.B., Pintos A.P.S. and Leo D.J. 2006. Processing contaminated soils and sediments bt high power ultrasound. Mineral Engineering 19:450-453.
Correia, L.M., Saboya. R.M.A., Campelo, N.S., Cecilia. J.A., Castellon, E.R-., Cavalcante. C.L. Jr. and Vieira, R.S. 2014. Characterization of calcium oxide catalysts from natural sources and their application in the transesterification of sunflower oil. Bioresource Technology 151:207-213, doi:10.1016/j.biortech.2013.10.046.
Cravotto, G. and Cintas, P. 2012. Introduction to sonochemistry: a historical and conceptual overview. In: Chen, D., Sharma, S.K. and Mudhoo, A. (Eds.) Handbook on Applications of Ultrasound – Sonochemistry for Sustainability. CRC Press. USA. 23-40.
de Mendonça V.R., Lopes O.F., Fregonesi R.P., Giraldi T.R. and Ribeiro C. 2014. TiO2-SnO2 heterostructures applied to dye photodegradation: The relationship between variables of synthesis and photocatalytic performance. Applied Surface Science 298:182-191.
Dewanto, D.P., Fransiskus, Wibisono, H.Y., Adnan, I.F. and Haidar, M. 2013. Report of Project Planning on Exploration of Lime Stone Deposition Mining. Faculty of Mining and Petroleum Engineering. Bandung Institute of Technology (in Indonesian).
Doll, T.E. and Frimmel, F.H. 2005. Removal of selected persistent organic pollutants by heterogeneous photocatalysis in water. Catalysis Today 101(3-4):195-202, doi:10.1016/j.cattod.2005.03.005.
Dong, H., Zeng, G., Tang, L., Fan, C. Zhang, C., He, X. and He, Y. 2015. An overview on limitations of TiO2-based particles for photocatalytic degradation of organic pollutants and the corresponding countermeasures. Water Research 79:128-146.
Environment Australia. 1997. Appropriate Technologies for the Treatment of Scheduled Wastes: Review Report Number 4. Department of the Environment, Water, Heritage and the Arts. Australian Government. Australia.
Esipovichk, A., Rogozhin, A., Danov, S., Beleusov, A. and Kanakov, E. (2018) The structure, properties and transesterification catalytic activities of the calcium glyceroxide. Chemical Engineering Journal 339:303-316.
Fitriani, K.C., Taufik, D., Wahyudi, K. and Hernawan. 2017. Synthesis of precipitated calcium carbonated with acid stearat as a surface modifier. Jurnal Keramik dan Gelas Indonesia 2(2):87-95 (in Indonesian).
Flores, R., Blass, G. and Dominguez, V. 2007. Soil remediation by an advanced oxidative method assisted with ultrasonic energy. Journal of Hazardous Materials 140:399-402, doi:10.1016/j.jhazmat.2006.09.044.
Garcia, H. and Ferrer, B. 2013. Photocatalysis by MOFs. In: Xamena, F.X.L. and Gascon, J.,(Eds.). Metal Organic Frameworks as Heterogeneous Catalyst. RSC Publishing. Cambridge. UK. 365-383.
Han, D., Li, Y. and Jia, W. 2010. Preparation and characterization of molecularly imprinted SiO2-TiO2 and photo-catalysis for 2, 4-dichlorophenol. Advanced Materials Letters 1(3):188-192.
Harder, S. 2010. From limestone to catalysis: application of calcium compounds as homogeneous catalysts. Chemical Review 110:3852-3876.
Herlambang, A., Sudaryanto, A., Mulyanto, A. And Aviantara, D.B. 2015. Destruction Technology for PCBs (Teknologi Destruksi PCBs). Researsh Report. Pusat Layanan Teknologi – BPPT (in Indonesian).
Huang, H., Jiang, J.G., Xiao Y. and Song, Y.C. 2015. Lab and pilot scale studies of chlorinated new POPs destruction using base-catalyzed dechlorination method. China Environmental Science 35(4):1149-1155.
Jimenez, J.C., Dachs, J. and Eisenreich, S.J. 2015. Atmospheric deposition of POPs: implications for the chemical pollution of aquatic environments. Comprehensive Analytical Chemistry 67:295-322.
Kang SH, Lee W. and Kim H.S. 2012. Effects of CdS sensitization on single crystalline TiO2 nanorods in photoelectrochemical cells. Material Letters 85:74-76.
Kouzu, M., Kasuno, T., Tajika, M., Sugimoto, Y., Yanamaka, S. and Hidaka, J. 2008. Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production. Fuel 7(12):2798-2806.
Kovner, K. 2017 Persistent Organic Pollutants: A Global Issue, A Global Response. Available at https://www.epa.gov/international-cooperation/persistent-organic-pollutants-global-issue-global-response (retrieved on 19 April 2019).
Lei, Z. 2015. Fate of POPs and its laboratorial technics under combined plants cultivation. Advanced Materials Research 1065-1069:3146-3150.
Levec, J. and Pintar, A. 2007. Catalytic wet-air oxidation processes: A review. Catalysis Today 124:172-184.
Li, F. 2012. Study on sono-photocatalytic degradation of POPs: A case study hydrating polyacrylamide in wastewater. In: Puzin, T. and Szlichtyng, A.M (Eds). Organic Pollutants Ten Years After the Stockholm Convention – Environmental and Analytical Update. InTech. Croatia. 327-344.
Li, Y., Wang, H., Zhang, J., Wang, J. and Miao, W. 2012 The industrial practice of POPs contaminated soil as alternative raw materials in clinker production. Procedia Environmental Sciences 16:641-645.
Liu, X., Piao, X., Wang, Y. and Zhu, S. 2008. Calcium ethoxide as a solid base catalyst for the transesterification of soybean Oil to biodiesel. Energy & Fuels 22(2):1313-1317.
Longwitz, L., Steinbauer, J., Spannenberg, A. and Werner, T. 2017. Calcium-based catalytic system for the synthesis of bio-derived cyclic carbonates under mild conditions. American Chemical Society (ACS) Catalysis 8(1):665-672.
Lukic, B., Panico, A., Huguenot, D., Fabbricino, M., van Hullebusch, E.D. and Esposito, G.2017. A review on the efficiency of landfarming integrated with composting as a soil remediation treatment. Environmental Technology Review 6(1):94-116.
Luo, J. and Lei, Z. 2014. Enhanced dissipation of POPs in soils by combined plants cultivation. Applied Mechanics and Materials 675-677:416-421.
Mahlambi, M.M., Ngila, C.J. and Mamba, B.B. 2015. Recent developments in environmental photocatalytic degradation of organic pollutants: The case of titanium dioxide zanoparticles-A review. Journal of Nanomaterials 2015:1-29.
Mahmiani, Y., Sevim, A.M. and Gul, A. 2016. Photocatalytic degradation of persistent organic pollutants under visible irradiation by TiO2 catalysts sensitized with Zn(II) and Co(II) tetracarboxy-phthalocyanines. Journal of Porphyrins Phthalocyanines 20:1190–1199.
Manuaba, I.B.P. 2007. Chlorinated organic pesticide contaminants in Buyan Lake Buleleng Bali. Jurnal Kimia 1(1):39-46 (in Indonesian).
Marinković, D.M., Stankovic, M.V., Velickovic, A.V., Avramović, J.M., Miladinović, M.R., Stamenković, O.O., Veljković, V.B. and Jovanović, D.M. 2016. Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives. Renewable and Sustainable Energy Reviews 56:1387-1408.
McDowall, R. and Vijgen, J. 2002. Destruction and Decontamination Technologies for PCBs and other POPs Wastes Under the Basel Convention: A training manual for hazardous waste project managers. Vol. C-Annexes. Secretariat of the Basel Convention. International Environment House. Switzerland.
McDowall, R. 2002. Destruction and Decontamination Technologies for PCBs and other POPs Wastes Under the Basel Convention: A training manual for hazardous waste project managers. Vol. A. Secretariat of the Basel Convention. International Environment House. Switzerland.
McDowall, R., Boyle, C., Graham, B. 2004. Review of Emerging, Innovative Technologies for the Destruction and Decontamination of POPs and the Identification of Promising Technologies for Use in Developing Countries. The Scientific and Technical Advisory Panel of the GEF United Nations Environment Programme and International Centre for Sustainability Engineering and Science, Faculty of Engineering, The University of Auckland, Auckland, New Zealand.
Megharaj, M. and Naidu, R. 2017. Soil and brownfield bioremediation. Microbial Biotechnology 10(5):1244-1249
Mehta, K., Jha, M.K. and Divya, N. 2018. Transesterification of Prunus armeniaca oil using calcium methoxide as a catalyst: Identification of methyl esters and proposed mechanistic pathways. Energy Sources Part A: Recovery, Utilization, and Environmental Effects:1-10.
Melnikova, T.V., Polyakova, L.P., Gordeev, A.V. and Oudalova, A.A. 2019. Radiation stability of lindane and active substance of hexachlorane dust preparation under electron irradiation. IOP Conference Series: Materials Science and Engineering 487:1-5.
Ministry of Energy and Mineral Resources Republic of Indonesia. 2014. Map of Indonesian Limestone Distribution. Indonesian Geological Agency (in Indonesian).
Ministry of Environment Republic of Indonesia. 2014. Review and Update of National Implementation Plan for Stockholm Convention on Persistent Organic Pollutants in Indonesia. Ministry of Environment Republic of Indonesia.
Nahas, A.C. 2009. Distribusi global persistent organic pollutants (POPs). Stasiun Pemantau Atmosfer Global Bukit Koto Tabang. Badan Meteorologi Klimatologi dan Geofisika.
Naval Facilities Engineering Service Center. 1997. Technology Transfer Report: Production Base Catalysed Decomposition Process, Guam, Mariana Islands (Technical Report: TR-2075-ENV). Port Hueneme. California. United States.
Pariatamby, A. and Kee, Y.L. 2016. Persistent organic pollutants management and remediation. Procedia Environmental Sciences 31:842-848.
Pi, Y., Li, X., Xia, Q., Wu, J., Li, Y., Xiao, J. and Li, Z. 2017. Adsorptive and photocatalytic removal of Persistent Organic Pollutants (POPs) in water by metal-organic frameworks (MOFs). Chemical Engineering Journal 337:351-371.
Pusat Sarana Pengendalian Dampak Lingkungan (Pusarpedal) (2014) Pemantauan Dan Kajian Pencemar Organik di Lingkungan Tahun 2014. Available at http://www.kelair.bppt.go.id/sib3pop/Iptek/PemantauanPOP2014/PemantauanPOP2014.htm (retrieved on 13 March 2019).
Rahuman, M.S.M.M., Pistone, L., Trifiro, F. and Miertus, S. 2000. Destruction technologies for polychlorinated biphenyls (PCBs). Proceedings of Expert Group Meetings on POPs and Pesticide Contamination: Remediation Technology and on Clean Technologies for The Reduction and Elimination of POPs. ICS-UNIDO.
The GTZ-Holcim Public Private Partnership. 2013. Guidelines on co-processing Waste Materials in Cement Production. Holcim Group Support Ltd and Deutsche Gesellschaft für Technische Zusammenarbeit (GTZ) GmbH Santoso, W.Y. 2009. The urgency for the ratification of the 2001 Stockholm Convention on Persistent Organic Pollutants for Indonesia. Mimbar Hukum 21(1):53-66 (in Indonesian).
Secretariat of the Stockholm Convention. 2019. Ninth Meeting of the Conference of the Parties to the Stockholm Convention. Available at http://chm.pops.int/TheConvention/ ConferenceoftheParties/Meetings/COP9/tabid/ 7521/Default.aspx (retrieved on 19 April 2019).
Shammi, M., Uddin, M.K., Malek, M.A. and Hasanuzzaman, M. 2007. Degradation of DDT by gamma-radiation in perspective of POPS management in Bangladesh. Journal of Agricultural Education and Tevhnology 10(1-2):15-20.
Shoiful, A., Fujita, H., Watanabe, I. and Honda, K. 2013. Concentrations of organochlorine pesticides (OCPs) residues in foodstuffs collected from traditional markets in Indonesia. Chemosphere 90:1742-1750.
Shresta, R.A., Mudhoo, A., Pham, T.D. and Sillanpaa, M. 2012. Ultrasound and sonochemistry in the treatment of contaminated soils by persistent organic pollutants. In: Chen, D., Sharma, S.K. and Mudhoo, A. (Eds.) Handbook on Applications of Ultrasound – Sonochemistry for Sustainability. CRC Press. USA. 407-418.
Sinulingga, K. 2006. Study of organochlor residues on Daucus carota L. carrots in the central district of Karo Regency, North Sumatra. Jurnal Sistem Teknik Industri 7(1):92-97 (in Indonesian).
Sorescu, M. and Xu, T. 2011. The effect of ball-milling on the thermal behavior of anatase-doped hematite ceramic system. Journal of Termal Analysis and Calorimetry 103(2):479-484.
Speight, J.G. 2017.Environmental Organic Chemistry for Engineers. Elsevier Inc. India.
Suharsih, Sudarto, Wihardjaka, A., Dewi, T., Sukarjo, Pramono, A., Wahyuni, S., Ariani, M. and Suryanto .2015. Annual Report 2015. Agricultural Environmental Research Institute. Agricultural Research and Development Agency. Ministry of Agriculture, Republic of Indonesia (in Indonesian).
Sukandarrumidi. 2009. Industrial Mining Materials. Gadjah Mada University Press. Yogyakarta. Indonesia (in Indonesian).
Sumartono, A. 2002. Decomposition of Pentachlorophenol in Water by Gamma Irradiation. Master Thesis, Bogor Agricultural University (in Indonesian).
Sun, M., Li, D., Chen, Y., Chen, W., Li, W., He, Y. and Fu, X. 2009. Synthesis and photocatalytic activity of calcium antimony oxide hydroxide for the degradation of dyes in water. Journal of Physical Chemistry C 113(31):13825–13831.
Suprapto, Fauziah, T.R., Sangi, M.S., Oetami, T.P., Qoniah, I. and Prasetyoko, D. 2016. Calcium oxide from limestoneas soild base catalyst in transesterification of Reutealis trisperma oil. Indonesian Journal of Chemistry 16(2):208-213.
Trifan, A. and Calinescu, I. 2009. Microwave assissted catalytic dechlorination of PCB. University Politehnica of Bucharest Scientific Bulletin 71(4):71-80.
Ulgen, A. and Hoelderich, W.F. 2011. Conversion of glycerol to acrolein in the presence of WO3/TiO2 catalysts. Applied Catalysis A: General 400(1-2):34-38.
United Nations Environment Programme (UNEP).2009. The Nine New POPs: an introduction to the nine chemicals added to the Stockholm Convention by the Conference of the Parties at its fourth meeting. Secretariat of the Stockholm Convention on Persistent Organic Pollutants. International Environment House. Switzerland.
United Nations Environment Programme (UNEP). 2012. Technical Guidelines on the Environmentally Sound Co-processing of Hazardous Waste in Cement Kilns. Secretariat of the Basel Convention. International Environment House. Switzerland.
United States Environmental Protection Agency (USEPA). 2017. Overview of wood preservative chemicals. Available at https://www.epa.gov/ingredients-used-pesticide-products/overview-wood-preservative-chemicals (retrieved on 4 April 2019).
Verma, A. K., Dash, R.R., and Bhunia, P. 2012. A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. Journal of Environmental Management 93(1):154-168.
Wang, C.C., Li, J.R., Lv, X.L., Zhang, Y.Q. and Guo, G. 2014. Photocatalytic organic pollutants degradation in metal–organic framework. Energy & Environmental Science 7(9):2831-2867.
Winarti, C. and Munarso, S.J. 2005. Study of dioxin contamination in food. Proceedings of the National Seminar on Postharvest Innovative Technologies for the Development of Agriculture-Based Industries. Center for Agricultural Research and Development. Agriculture Department. Bogor.. Indonesia, 1208-1217 (in Indonesian).
Zacharia, J.T. 2019. Degradation pathways of persistent organic pollutants (POPs) in the environment. In: S.K. Donyinah, S.K (Ed), Persistent Organic Pollutants. InTechopen 17-29.
Zeng, L., Guo, X., He, C. and Duan, C. 2016. Metal-organic frameworks: versatile materials for heterogeneous photocatalysis. ACS Catalysts 6(11):7935-7947.
Zinoviev, S., Fornasiero, P., Lodolo, A. and Miertus, S. 2007. Non-combustion technologies for POPs destruction: review and evaluation. International Centre for Science and High Technology. United Nations Industrial Development Organisation, Pure and Applied Chemistry, Trieste, Italy.
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