Geochemical study of ultramafic rocks from Latowu area of North Kolaka, Southeast Sulawesi and its implication for CO2 sequestration

Authors

  • S Sufriadin Department of Mining Engineering, Hasanuddin University
  • Sri Widodo Department of Mining Engineering, Hasanuddin University, Jl.Poros Malino Km.6 Gowa 92171, South Sulawesi
  • Akane Ito Environmental Geology Laboratory, Division of Sustainable Resources, Graduate Study of Engineering, Hokkaido University, Sapporo 060-8628, Japan
  • Tsubasa Otake Environmental Geology Laboratory, Division of Sustainable Resources, Graduate Study of Engineering, Hokkaido University, Sapporo 060-8628, Japan
  • Kenzo Sanematsu Geo Resources Group, The National Institute of Advance Science and Technology (AIST), Tsukuba, Ibaraki 305-8561, Japan

DOI:

https://doi.org/10.15243/jdmlm.2018.054.1403

Keywords:

carbon dioxide, sequestration, serpentine, Sulawesi, ultramafic rocks

Abstract

Geochemistry of ultramafic rocks in the Latowu Area of North Kolaka Regency, Southeast Sulawesi has been investigated with the aim at deciphering of mineral characteristics, chemical composition and their potential use as carbon dioxide storage. Mineralogy was characterized by both scanning electron microscopy (SEM) and X-ray diffractometry (XRD); whereas bulk rock and mineral chemistry were analyzed by means of X-ray fluorescence spectrometry (XRF) and Electron probe microanalyzer (EPMA) respectively. Results of analyses show that lizardite is predominant serpentine mineral present, followed by chrysotile and trace amount of magnetite. Remnants of olivine and pyroxene were detected in some samples but they have been pseudomorphicly replaced by serpentine. Serpentinization of Latowu ultramafic rocks has led to decrease in grain size and density. Lizardite is characterized by fine grained particles with higher in iron. The higher Mg and Fe of the rocks indicate a suitability as feed materials for carbon dioxide sequestration. Mineral and chemical properties of ultramafic rocks have significant role in evaluating the feasibility of mineral carbonation.

References

Aminu, M.D., Nabavi, S.A., Rochelle, C.A. and Manovic, V. 2017. A review of developments in carbon dioxide storage. Applied Energy 208: 1389-1419.

Deer, W.A., Howie, R.A. and Zussman, J. 1992, An introduction to the rock-forming minerals, Prentice Hall, Harlow, p. 696.

Dlugogorski, B.Z. and Balucan, R.D. 2014. Dehydroxilation of serpentine minerals: Implication fro mineral carbonation. Renewable and Sustainable Review 21: 353-367

Evans, B.W. 2008. Control of the products of serpentinization by the Fe2+Mg-1 exchange potential of olivine and orthopyroxene. Journal of Petrology 49 (10): 1873 – 1887.

Goff, F. and Lackner, K.S.1998. Carbon dioxide sequestering using ultramafic rocks. Environmental Geoscience 5: 81 – 101.

Hirasawa, R. and Horita, H. 1987. Dissolution of nickel and magnesium from garnierite ore in an acid solution. International Journal of Mineral Processing 19: 273-284.

Kadarusman, A., Miyashita, S., Maruyama, S., Parkinson, C.D. and Ishikawa, A. 2004. Petrology, geochemistry and paleogeographic reconstruction of the East Sulawesi Ophiolite, Indonesia. Tectonophysics 392: 55 – 83.

Kharaka, Y.K., Cole, D.R., Thordsen, J.J., Gans, K.D., and Thomas, R.B. 2013. Geochemical Monitoring for Potential Environmental Impacts of Geologic Sequestration of CO2, in DePaolo, D.J., Cole, D.R., Navrotsky, A., Bourg, I.C. (Eds).), Geochemistry of Geologic CO2 Sequestration, Reviews in Mineralogy & Geochemistry 77: 399-430.

Krevor, S.C., Bravesa, C.R., Van Gosenb, B.S. and McCaffertyb, A.E. 2009. Delineation of Magnesium-rich Ultramafic Rocks Available for Mineral Carbon Sequestration in the United States. Energy Procedia 1: 4915-4920.

Lackner, K.S., Wendt, C.H., Butt, D.P., Joyce, E.L. and Sharp, D.H. 1995. Carbon dioxide disposal in carbonate minerals. Energy 20: 1153-1170.

Liu, K., Chen, Q.Y., Hu, H.P. and Yin, Z. 2010. Characterization and leaching behavior of lizardite in Yunjiang laterite ore. Applied Clay cience 47:, 311 – 16.

Mani, D., Charan, S.N. and Kumar, B. 2008. Assessment of carbon dioxide sequestration potential of ultramafic rocks in the greenstone belt of southern India. Current Science 94(1): 53-60.

Olajire, A.A. 2013. Carbon dioxide sequestration by mineral carbonation technology: A state-of-the-art review. Journal of Petroleum Science and Technology 109: 364-392

Olivier, J.G.J., Schure, K.M. and Peters, J.A.H.W. 2017, Trend in Global CO2 and Total Greenhouse Gas Emissions, PBL Netherlands Environmental Assessment Agency.

Sanna, A., Uibu, M., Caramanna,G., Kuusik, R. and Maroto-Valer, M.M. 2014. A review of mineral carbonation technologies to sequester CO2. Chemical Society Reviews 43: 8049—8080.

Seifritz, W. 1990. CO2 disposal by means of silicates. Nature 345: 486.

Styles, M.T., Sanna, A., Lacinska, A.M., Nadem, J. and Maroto-valer, M. 2014. The variation in composition of ultramafic rocks and the effect on their suitability for carbon dioxide sequestration by mineralization following acid leaching. Greenhouse Gasses: Science and Technology 4: 1-12.

Sufriadin, Idrus, A., Pramumijoyo, S., Warmada, I.W. and Imai, A. 2011. Studies on mineralogy and chemistry the saprolitic nickel ore from Soroako Indonesia: Implication for the lateritic ore processing. Journal of Southeast Asian Applied Geology 3: 23-33.

Tahirkheli, T., Bilqess, R., Abbas, S.M. and Zakir, S. 2012. CO2 mineral sequestration studies in the ultramafic rocks of northern Pakistan, Journal of Himalayan Earth Science 45 (1): 83-90.

Wang, F., Dreisinger, D.B., Jarvis, M. and Hitchins, T. 2017. The technology of CO2 sequestration by mineral carbonation: current status and future prospects. Canadian Metallurgical Quarterly 1-13.

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Submitted

24-06-2018

Accepted

27-06-2018

Published

01-07-2018

How to Cite

Sufriadin, S., Widodo, S., Ito, A., Otake, T., & Sanematsu, K. (2018). Geochemical study of ultramafic rocks from Latowu area of North Kolaka, Southeast Sulawesi and its implication for CO2 sequestration. Journal of Degraded and Mining Lands Management, 5(4), 1403–1408. https://doi.org/10.15243/jdmlm.2018.054.1403

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Section

Research Article